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Nunatak People who are trusting by nature tend to be taken advantage of most often. Children have to be trusting by nature in order to survive in a world where they have no real autonomy. We're setting them up to fail if we don't try to protect them and instead let them fend for themselves.
There are lots of ways we teach children to self-regulate, from time-outs and detention, to the teaching of abstinence, to anti-bullying, anti-drug, or anti-distracted driving campaigns, and even to stranger danger exercises. And many of them end up running into these problems we're trying to prevent anyway because they don't have the experience to really understand the consequences of their actions. Not until it's too late for a few of them.
That said, there are already mental health sites established by professionals that are better at addressing many common problems facing young people. Asking children to gamble their future well-being on the intentions of online strangers is incredibly negligent. Many predators know how to exploit vulnerabilities, which makes them more than capable of outwitting a child that may feel lost and desperate.
I agree that we can't protect our children from everything, but this issue is a no-brainer for me. Anonymity is a criminal's best friend, and websites like these are designed around anonymity