When do we elect our electoral voters?

I don't get it...

If our electoral voters vote for the president and the state elects the electoral voters, why should I even vote? I don't ever recall voting for the electors in California. I don't even know who they are!? So, why should I even vote?

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Theosis · 56-60, M

California has 55 electoral voters. When then do they vote? After all Californians have voted? They cast they vote at 11pm or later after their states popular vote has completed voting?