Not in the sense of it being toxic for them or anything, but it doesn't contain the right nutritional value ducks need and can fill a duck's stomach to where they don't have room for other foods they would naturally eat that are healthy for them and can lead to malnutrition.
Next time you plan on going to the park or some place where there's ducks you like to feed, here are some healthier alternatives to bread you can feed them:
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