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The Vatican City, but that's kind of a cheat. The second smallest is Monaco. In terms of population it's Tuvalu, some islands in the Pacific.
Tracos · 51-55, M
actually... pitcairn islands only have 50 inhabitants.... tuvalu has 11,000
https://www.cia.gov/library/publications/the-world-factbook/fields/335rank.html
https://www.cia.gov/library/publications/the-world-factbook/fields/335rank.html